Is dimethyl silicone oil emulsion suitable for rendering glass fiber hydrophobic?
Source:AI+MODIFY Author:QL CHEMICAL Release time:2026-07-24 16:51 Reading times:125

Conventional Dimethyl Silicone Oil Emulsion

I. Product Properties

Conventional dimethyl silicone oil emulsion consists of linear polydimethylsiloxane, emulsifier and water. Its molecules contain no reactive groups such as hydroxyl groups or silicon-hydrogen bonds, so crosslinking cannot occur. The emulsion only adheres to the surface of glass fibers via emulsifiers and forms a film through physical adsorption.
It is commonly known as soft silicone emulsion, mold-release silicone emulsion and general waterproof silicone emulsion in the market.

II. Advantages for Hydrophobic Treatment of Glass Fiber

  1. Low cost with high cost performance and affordable raw materials.
  2. Instant hydrophobic effect: water beads form distinctly right after treatment.
  3. It provides lubrication simultaneously, making glass fibers smooth, less prone to fuzzing and fluffier.
  4. Water-based system with simple dilution, stable at ambient temperature and resistant to demulsification at low concentrations.
  5. It does not affect the whiteness of glass fibers and will not cause yellowing.

III. Critical Drawbacks (Major Defect for Long-term Waterproofing of Glass Fiber)

  1. Extremely poor adhesion and non-durable hydrophobicity
    Without chemical bonding with glass fibers, the silicone merely floats on the surface. When exposed to water washing, rain or high-humidity environments, the silicone is quickly washed away, and the hydrophobic performance declines sharply within a few days. It is completely unsuitable for outdoor use or filter materials.
  2. Prone to migration and oil bleeding under high temperature
    During drying or post-processing of glass fibers above 200℃, the silicone oil will separate and bleed out freely, leaving oily surfaces on glass fibers, sticking rollers and finished products. Subsequent resin lamination or film lamination will suffer delamination, poor adhesion and failure of printing performance.
  3. Non-dense film layer with poor soaking resistance
    Waterproof performance fails completely after prolonged soaking, only suitable for short-term moisture-proofing.
  4. Silicone easily rubs off
    Hydrophobicity deteriorates rapidly after repeated rubbing of glass fiber felts and filter cotton.

IV. Applicable Glass Fiber Scenarios Only (Short-term Indoor Moisture Resistance Only)

  1. Disposable indoor glass fiber cotton and packaging filling glass fibers requiring short-term moisture resistance in dry environments.
  2. Low-end glass fiber semi-finished products that only need lubrication and temporary waterproofing without long-term rain or water immersion exposure.
  3. Simple semi-finished glass fiber products without resin lamination or high-temperature post-processing.

V. Completely Unsuitable Scenarios

Outdoor glass fiber, dust removal filter cotton, water filtration glass fiber, waterproof glass fiber boards, products requiring subsequent composite bonding, and work conditions with long-term humidity exposure.

VI. On-site Application Process of Conventional Silicone Emulsion for Glass Fiber

  1. Dilution ratio: dilute with clean water to a working liquid solid content of 5%–10%.
  2. Application methods: spray, pad dip, or mix a small amount into glass fiber sizing agent.
  3. Drying conditions: only evaporate moisture at 80–120℃; higher temperatures will accelerate silicone oil separation and oil bleeding.
  4. Dosage: 0.2%–0.5% by dry weight of glass fiber; excessive dosage inevitably causes fiber adhesion due to oil bleeding.
  5. Compatibility taboo: anionic conventional silicone emulsion cannot be mixed with cationic sizing agents or cationic additives, otherwise direct demulsification and stratification will occur.

VII. Low-cost Compounding Formulas for Improved Durability

Used alone, the emulsion delivers poor long-term water resistance. Compound formulas are available to extend waterproof lifespan:
  1. Mix conventional silicone emulsion and hydroxyl silicone emulsion at a ratio of 7:3. The introduced crosslinkable groups greatly enhance resistance to water washing.
  2. Add a small amount of water-based silane coupling agent KH550. The silane anchors to the silica surface of glass fibers to lock the silicone layer and reduce shedding and migration.

VIII. Performance Comparison: Conventional Silicone Emulsion vs. Hydroxyl Reactive Silicone Emulsion


Performance Conventional Dimethyl Silicone Oil Emulsion Hydroxyl-terminated Silicone Emulsion
Molecular reactivity No reactive groups, incapable of crosslinking Si-OH groups at both ends, self-crosslinks under heating
Bonding mode with glass fiber Physical adsorption, easy shedding Chemical anchoring to form dense silicone film
Durability of hydrophobicity Short-term, fails within days Resists water washing and rain for months
High-temperature stability Severe oil bleeding and migration above 200℃ Rare oil bleeding below 250℃
Compatibility with resin composite Poor, prone to debonding and delamination Good, low silicone separation
Unit price Low Slightly higher

Summary & Recommendations

  1. Choose conventional dimethyl silicone oil emulsion for temporary short-term waterproofing in dry indoor environments with limited budget.
  2. For glass fibers requiring long-term hydrophobicity, water contact, outdoor service, filter material application or subsequent composite bonding: Do not use conventional dimethyl silicone oil emulsion alone. Prioritize hydroxyl self-crosslinking silicone emulsion, or improve performance by compounding hydroxyl silicone emulsion with silane coupling agent.


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