How to Solve the Non-Spreading Issue of Amino Silicone Oil on Steel Plates?
Source:AI+MODIFY Author:QL CHEMICAL Release time:2026-01-26 11:49 Reading times:9

Core Solution: Aiming at the non-spreading problem of 1000cst amino silicone oil on steel plates, the core is to reduce surface tension and optimize film-forming spreadability. Combined with the characteristics of the medium-high viscosity of 1000cst, three types of practical solutions are proposed: direct modification (formula adjustment), process optimization and substrate pretreatment, with specific parameters and operating methods attached.

I. Direct Formula Adjustment (Most Core, Adapted to 1000cst System)

1000cst amino silicone oil itself has high intermolecular force and relatively high surface tension (about 30~35mN/m), while steel plates have low surface energy (cold-rolled steel plates about 28~32mN/m), which is prone to poor spreading and edge shrinkage. It is necessary to reduce the system surface tension to 25~28mN/m (matching the surface energy of steel plates) by adding spreading additives or blending silicone oil, without affecting the film-forming, slip and adhesion properties of amino silicone oil.

Solution 1: Add Special Non-Ionic Spreading Additives (Highly Recommended, Strong Practicability)

  • Selection Parameters: Choose polyether-modified silicone spreading agents (compatible with amino silicone oil) with surface tension ≤24mN/m, HLB value 8~12 and effective content ≥98%. Avoid ionic additives (which will damage the film formation of amino silicone oil).
    Recommended models: BYK-306, Dow Corning DC-51, Shin-Etsu KF-6011 (all industry universal, infinitely miscible with 1000cst amino silicone oil).
  • Addition Amount: 0.2%~0.8% (based on the total mass of amino silicone oil), ≤1% (excess will cause sticky film formation and reduced slip property).
  • Operation Method: Dilute the spreading agent with a small amount of xylene/white mineral oil (1:1), add it slowly while stirring the amino silicone oil (300~500rpm), and stir for 10~15min until a homogeneous phase is formed without delamination.

Solution 2: Blending with Low-Viscosity Silicone Oil (Auxiliary Viscosity Reduction + Improve Spreading, No Change to Main Components)

Blend low-viscosity dimethyl silicone oil/amino-modified silicone oil with 1000cst amino silicone oil to reduce the overall viscosity of the system, improve molecular fluidity, and maintain the core properties of amino silicone oil at the same time.
  • Selection Parameters: Dimethyl silicone oil (50~100cst, CAS 9006-65-9) or low-amine value amino silicone oil (500cst, amine value 0.2~0.4mmol/g).
  • Blending Ratio: 1000cst amino silicone oil : low-viscosity silicone oil = 9:1 ~ 8:2 (the viscosity of the blended system is about 800~900cst, the spreadability is increased by more than 30%; if the ratio is >1:1, the film-forming adhesion will decrease).

Solution 3: Dilution with Trace Polar Solvent (Emergency Solution, Suitable for Small-Batch Trial)

If no special additives are available, add high-boiling polar solvent to reduce surface tension. The solvent must meet the requirements: non-corrosive, not too volatile, and miscible with amino silicone oil.
  • Selection: Ethylene glycol monobutyl ether (EB, CAS 111-76-2), dipropylene glycol methyl ether (DPM, CAS 34590-94-8). DPM is preferred (low odor, better compatibility with amino silicone oil).
  • Addition Amount: 1%~3% (excess will cause slow film-forming drying and pinholes). Stir until completely dissolved before use.

II. Steel Plate Substrate Pretreatment (Eliminate Surface Impurities, Improve Surface Energy, Basic Premise)

Oil stains, oxide layers and dust on the steel plate surface are important causes of poor spreading (oil stains will reduce the surface energy to below 25mN/m, making silicone oil completely unwettable). Pretreatment must be carried out first to ensure the surface cleanliness is ≥95%.
  1. Degreasing Treatment: Spray/soak the steel plate with neutral degreaser (concentration 3%~5%, temperature 40~50℃) for 5~10min, rinse with clean water and dry (no water marks or oil film on the surface);
  2. Activation Treatment (Optional, for cold-rolled/galvanized steel plates): Wipe the surface with dilute phosphoric acid (concentration 1%~2%) to remove the oxide layer, rinse with clean water and dry, so that the surface energy of the steel plate is increased to 35~40mN/m, which greatly improves the wettability of silicone oil;
  3. Dust-Free Operation: Operate the pretreated steel plate in a clean room (cleanliness ≥100,000 class) to avoid secondary contamination.

III. Construction Process Optimization (Adapted to 1000cst Viscosity, Improve Spreading Uniformity)

1000cst is of medium-high viscosity, and conventional brush coating is prone to brush marks and material accumulation. It is necessary to adjust the construction method and process parameters to allow sufficient flow and spreading time (30~60s) for silicone oil on the steel plate surface:
  1. Construction Method: Prioritize microgravure roll coating or air atomization spraying instead of brush coating/knife coating;
    • Roll coating: Select 100~120 mesh microgravure roll, roll speed 10~15m/min, pressure 0.1~0.2MPa to ensure uniform transfer of silicone oil to the steel plate surface;
    • Spraying: Spray gun nozzle diameter 0.8~1.0mm, spraying pressure 0.3~0.4MPa, gun distance 20~30cm, thin coating for 2~3 times (wet film thickness 5~8μm/time) to avoid material accumulation due to thick coating.
  2. Construction Temperature: Control at 25~35℃, humidity ≤60%; low temperature (<15℃) will lead to increased viscosity and decreased fluidity of silicone oil, while high temperature (>40℃) will cause rapid solvent volatilization, and silicone oil forms a film before spreading.
  3. Pre-Drying Treatment: After coating, pre-dry at 60~80℃ for 5~10min to allow full spreading of silicone oil, then raise the temperature to the curing temperature (120~150℃) for curing to avoid edge shrinkage caused by direct high-temperature curing.

IV. Key Notes (Avoid Solution Failure, Ensure Stability)

  1. Conduct compatibility tests for all additives/solvents with 1000cst amino silicone oil (stir at room temperature and stand for 24h, no delamination or precipitation means compatibility);
  2. The amine value of amino silicone oil must match: if the amine value is too high (>0.8mmol/g), the molecular polarity is too strong and easy to agglomerate, resulting in decreased spreadability. It is recommended to control the amine value at 0.4~0.6mmol/g (conventional matching amine value for 1000cst);
  3. Film thickness control: wet film thickness ≤20μm, dry film thickness 8~12μm. Thick film is prone to sagging and edge shrinkage, while thin film is easier to spread uniformly;
  4. Curing process: curing temperature 120~150℃, time 15~20min. Insufficient curing will lead to sticky film formation and poor adhesion, which indirectly affects the film-forming effect after spreading.

V. Effect Verification Standards

After treatment, the amino silicone oil should achieve 100% spreading on the steel plate surface without edge shrinkage, pinholes or material accumulation. After film formation, the adhesion grade tested by cross-hatch cutter is ≥0, the surface is smooth and non-sticky to the touch, and no film peeling or yellowing occurs after being placed in high temperature and high humidity environment (40℃, 90%RH) for 48h.


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